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發佈日期：2014年6月18日
Mi. 18.06.2014 21:00, Stadion: Estadio do Maracana, Rio de Janeiro

Spanien:
1 GK Iker Casillas (c) 20 May 1981 (aged 33) 154 Spain Real Madrid
2 DF Raúl Albiol 4 September 1985 (aged 28) 46 Italy Napoli
3 DF Gerard Piqué 2 February 1987 (aged 27) 60 Spain Barcelona
4 MF Javi Martínez 2 September 1988 (aged 25) 17 Germany Bayern Munich
5 DF Juanfran 9 January 1985 (aged 29) 8 Spain Atlético Madrid
6 MF Andrés Iniesta 11 May 1984 (aged 30) 97 Spain Barcelona
7 FW David Villa 3 December 1981 (aged 32) 96 Spain Atlético Madrid
8 MF Xavi 25 January 1980 (aged 34) 132 Spain Barcelona
9 FW Fernando Torres 20 March 1984 (aged 30) 107 England Chelsea
10 MF Cesc Fàbregas 4 May 1987 (aged 27) 89 Spain Barcelona
11 FW Pedro 28 July 1987 (aged 26) 40 Spain Barcelona
12 GK David de Gea 7 November 1990 (aged 23) 1 England Manchester United
13 MF Juan Mata 28 April 1988 (aged 26) 33 England Manchester United
14 MF Xabi Alonso 25 November 1981 (aged 32) 111 Spain Real Madrid
15 DF Sergio Ramos 30 March 1986 (aged 28) 117 Spain Real Madrid
16 MF Sergio Busquets 16 July 1988 (aged 25) 65 Spain Barcelona
17 MF Koke 8 January 1992 (aged 22) 8 Spain Atlético Madrid
18 DF Jordi Alba 21 March 1989 (aged 25) 26 Spain Barcelona
19 FW Diego Costa 7 October 1988 (aged 25) 2 Spain Atlético Madrid
20 MF Santi Cazorla 13 December 1984 (aged 29) 64 England Arsenal
21 MF David Silva 8 January 1986 (aged 28) 80 England Manchester City
22 DF César Azpilicueta 28 August 1989 (aged 24) 6 England Chelsea
23 GK Pepe Reina 31 August 1982 (aged 31) 32 Italy Napoli

Chile:
1 GK Claudio Bravo (c) 13 April 1983 (aged 31) 79 Spain Real Sociedad
2 DF Eugenio Mena 18 July 1988 (aged 25) 25 Brazil Santos
3 DF Miiko Albornoz 3 November 1990 (aged 23) 2 Sweden Malmö FF
4 MF Mauricio Isla 12 June 1988 (aged 26) 47 Italy Juventus
5 MF Francisco Silva 11 February 1986 (aged 28) 12 Spain Osasuna
6 MF Carlos Carmona 21 February 1987 (aged 27) 44 Italy Atalanta
7 FW Alexis Sánchez 19 December 1988 (aged 25) 67 Spain Barcelona
8 MF Arturo Vidal 22 May 1987 (aged 27) 54 Italy Juventus
9 FW Mauricio Pinilla 4 February 1984 (aged 30) 27 Italy Cagliari
10 MF Jorge Valdívia 3 October 1983 (aged 30) 57 Brazil Palmeiras
11 FW Eduardo Vargas 20 November 1989 (aged 24) 30 Spain Valencia
12 GK Cristopher Toselli 22 June 1988 (aged 25) 4 Chile Universidad Católica
13 DF José Rojas 3 June 1983 (aged 31) 19 Chile Universidad de Chile
14 MF Fabián Orellana 27 January 1986 (aged 28) 26 Spain Celta Vigo
15 MF Jean Beausejour 3 June 1984 (aged 30) 59 England Wigan Athletic
16 MF Felipe Gutiérrez 8 October 1990 (aged 23) 18 Netherlands Twente
17 DF Gary Medel 3 August 1987 (aged 26) 61 Wales Cardiff City
18 DF Gonzalo Jara 29 August 1985 (aged 28) 65 England Nottingham Forest
19 MF José Pedro Fuenzalida 22 February 1985 (aged 29) 23 Chile Colo-Colo
20 MF Charles Aránguiz 17 April 1989 (aged 25) 21 Brazil Internacional
21 MF Marcelo Díaz 30 December 1986 (aged 27) 21 Switzerland Basel
22 FW Esteban Paredes 1 August 1980 (aged 33) 35 Chile Colo-Colo
23 GK Johnny Herrera 9 May 1981 (aged 33) 8 Chile Universidad de Chile